Inconel 600 corrosion
Does anyone know about corrosion problems of inconel alloys in CO/CO2 bearing gas (probable formation of nickel-tetra carbonyl)at temperature below 200°C.
That should be a slow ground ball for Inconel 600. It is designed for much worse environments.
I know that Ni is extracted by a water gas containing C0 which at a
temperature of about 50°C forms Ni(CO)4 , this complex at temperature
above 250°C decompose again to Ni + 4CO. It possible that the same gas
in contact with a nickel alloy at the above mentioned temperature
extract selectively the nickel? I haven't found any reference about
this in corrosion literature, but i think this is a normal process of
nickel production.
"The leaching of Ni from Ni-containing alloys by CO(g) does not appear
in the general corrosion literature because these alloys normally have a
protective oxide surface. It is more of a laboratory & very
specialized industry process."
Probably all commercial alloys of
common metals [not gold] come from the mill with an oxide film. The
carbonyl formation can only happen if you clean the metal and expose it
to CO(g) without heating in air, or if you reduced the surface oxide at
some higher temperature and then cooled in a strongly reducing
atmosphere.
I have removed surface oxides from both iron and cobalt
samples by the latter method. Used a silica glass tube inside a tube
furnace, with plug valve and inlet valve at one end and a stopcock at the
other, burning off high-purity H2 as it exited. After cooling, I closed
the valves and transferred the whole thing to a glovebox containing high
purity 'gettered' argon. In such a manner, one can perform reactions
normally prevented by the passive oxide film.
The thin amorphous
oxide that forms on an alloy at low/room temperature normally differs
in composition from the high temperature, crystalline oxide. The metal
ratio of the low temperature oxide is much closer to that of the alloy,
whereas the composition of the high temperature oxide is primarily
determined by the thermodynamic stabilities of the component oxides and
the activities of the metals in the alloy. This is why it is necessary
to passivate SS, to increase the Cr/Fe ratio of the low temperature
amorphous oxide. Whereas, the oxide that forms at higher temperature is
naturally Cr2O3-rich.
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